TS2023 MartinaK

Long-acting in-situ forming implants (ISFI) for TB and other infectious diseases.

Speaker: Martina Kovarova, Associate Professor, International Center for the Advancement of
Translational Science, Department of Medicine, Division of ID, UNC at Chapel Hill

Background

  • LTBI (TB infection without symptoms) affects 25% of world population – approximately 2 billion.
  • TB prevention therapy prevents LTBI from progressing to active TB and TBI in high-risk populations.
  • Current therapies: 6- to 9-month INH QD; 4-month RIF QD; 1HP QD; and 3HP QW.

Development of LA formulations of anti-TB drugs.

  • Focus on rifamycins (rifampin [RIF], rifapentine [RFP], and rifabutin [RFB]) due to potent bactericidal activity and ability to inhibit DNA-dependent RNA synthesis.
  • Rifabutin selected as a model drug for development of an ISFI formulation.
    • Reduced potential for DDIs – more suitable for TB-HIV coinfections.
    • Higher tissue uptake due to high lipophilicity, larger volume of distribution, longer terminal half-life, lower minimum inhibitory concentration (MIC).
    • Available as a low-cost generic medication.
  • ISFI technology for a LA RFB formulation.
    • Several FDA-approved products.
    • A biodegradable implant is formed after direct injection – no need to remove but can be removed to stop drug delivery.
    • Comprises three components that can be optimized – biodegradable polymer (PLGA), biocompatible solvent (DMSO/NMP), and the drug.

Analysis of ISFI formulation release properties in mice.

  • After injection into the hydrophilic SC space, there is an exchange between solvent and body fluid, and the implant becomes solid.


     

  • A single-dose yields plasma RFB concentrations above MIC for 18 weeks.


     

  • Additives can increase RFB solubility and drug load (i.e., solubility in DMSO vs DMSO + additives) and improve release properties (in-vitro dissolution studies and in vivo studies).

Evaluation of final optimized RFB-LA formulation (RFB14KH) in mice.

  • PK and tissue penetration.
    • SD + booster at month 2 or 3 – plasma RFB concentrations above MIC for 36 weeks (exceeds duration of all treatment options for LTBI).
    • Better tissue penetration than previously published (nearly 20:1 lung to plasma ratio).

  • In-vivo efficacy I (RFB14KH).
    • pre-exposure treatment or placebo for 14 days, exposed to Mtb aerosol at day 0, and necropsy at day 1 through 28.
      • All treated mice had bacterial load below level of detection (lung, liver, spleen).
      • All placebo mice had high bacterial load (lung, liver, spleen).
  • In vivo efficacy II (RFB14KH).
  • Exposed to Mtb aerosol at day 0, post-exposure treatment or placebo at day 7, and necropsy at day 1, 7 and 28.
  • Day 7– all mice have bacteria in the lung and no dissemination to liver or spleen.
  • Day 28 – all treated mice had bacterial load below level of detection in lung, liver, and spleen; all placebo mice had high bacterial load in all three tissues.

Continued optimization efforts achieved increased drug load and plasma concentration after a single injection.

Summary

  • We developed a LAI RFB formulation made of biodegradable polymer and biocompatible solvent that solidifies after SC injection.
  • Addition of additives (amphiphilic compounds) increases drug solubility in organic solvent, allowing significantly increased formulation drug load.
  • Translational relevance in mice.
    • Delivered high plasma drug concentrations for 16 weeks without need for removal.
    • Prevented acquisition of Mtb infection.
    • Cleared acute Mtb infection from the lung and prevented dissemination to other tissues.
  • A recently developed, optimized RFB-LA formulation (F4) delivers 4-fold more RFB.
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